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Article #5: Discover the importance of Calcium

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Calcium is the chemical element in the by heating and carefully adding water to
periodic table that has the symbol Ca and limestone. When lime is mixed with sand,
atomic number 20. Calcium is a soft grey it hardens into a mortar and is turned
alkaline earth metal that is used as a into plaster by carbon dioxide uptake.
reducing agent in the extraction of Mixed with other compounds, lime forms an
thorium, zirconium and uranium. Calcium important part of Portland cement.
is also the fifth most abundant element When water percolates through limestone
in the Earth's crust. It is essential for or other soluble carbonate rocks, it
living organisms, particularly in cell partially dissolves part of the rock and
physiology, and is the most common metal causes cave formation and characteristic
in many animals. stalactites and stalagmites and also
Notable characteristics Calcium is a forms hard water. Other important calcium
rather soft, grey, metallic element that compounds are nitrate, sulfide, chloride,
can be extracted by electrolysis from carbide, cyanamide, and hypochlorite.
calcium fluoride. It burns with a Isotopes Calcium has four stable isotopes
yellow-red flame and forms a white (40Ca and 42Ca through 44Ca), plus two
nitride coating when exposed to air. It more isotopes (46Ca and 48Ca) that have
reacts with water, displacing hydrogen such long half-lives that for all
and forming calcium hydroxide. practical purposes they can be considered
Calcium is essential in muscle stable.
contraction, oocyte activation, building It also has a cosmogenic isotope,
strong bones and teeth, blood clotting, radioactive 41Ca, which has a half-life
nerve impulse transmission, regulating of 103,000 years. Unlike cosmogenic
heartbeat, and fluid balance within isotopes that are produced in the
cells. In the U.S., between about 50% and atmosphere, 41Ca is produced by neutron
75% of adults do not get sufficient activation of 40Ca. Most of its
calcium in their diet. Adults need production is in the upper metre or so of
between 1,000 and 1,300 mg of calcium in the soil column where the cosmogenic
their daily diet. neutron flux is still sufficiently
The most abundant isotope, 40Ca, has a strong. 41Ca has received much attention
nucleus of 20 protons and 20 neutrons. in stellar studies because it decays to
Its electron configuration is: 2 41K, a critical indicator of solar-system
electrons in the K shell (principal anomalies.
quantum number 1), 8 in the L shell Naturally occurring calcium is 97% in the
(principal quantum number 2), 8 in the M form of 40Ca. 40Ca is one of the daughter
shell (principal quantum number 3), and 2 products of 40K decay, along with 40Ar.
in the N shell (principal quantum number While K-Ar dating has been used
4). The outer shell is the valence shell, extensively in the geological sciences,
with 2 electrons in the lone 4s orbital, the prevalence of 40Ca in nature has
the 3p orbitals being empty. impeded its use in dating.
Occurrence Calcium is not naturally found Techniques using mass spectrometry and a
in its elemental state. Calcium is found double spike isotope dilution have been
mostly in soil systems as limestone, used for K-Ca age dating.
gypsum and fluorite. Stalagmites and Dietary calcium supplements There are
stalactites contain calcium carbonate. conflicting recommendations about when to
Being an essential macromineral in the take calcium supplements.
human diet, soil conservation practices However, most experts agree that no more
often consider the sustainable than 500 mg should be taken at a time –
equilibrium of calcium concentrations in any excess will go to waste. It is
the earth. recommended to spread doses throughout
Applications Calcium is an important the day, with the last dose near bedtime.
component of a healthy diet. A deficit Recommended daily calcium intake varies
can affect bone and tooth formation, from 1000 to 1500 milligrams, depending
while overretention can cause kidney upon the stage of life.
stones. Vitamin D is needed to absorb Calcium carbonate is the most common and
calcium. Dairy products, such as milk and least expensive calcium supplement. It
cheese, are a well-known source of can be difficult to digest and causes gas
calcium. However, some individuals are in some people. Taking magnesium with it
allergic to dairy products and even more can help to prevent constipation.
people, particularly those of Calcium carbonate is 40% elemental
non-European descent, are calcium. 1000 mg will provides 400 mg of
lactose-intolerant, leaving them unable calcium. Take this supplement with food
to consume dairy products. to aid in absorption.
Fortunately, many other good sources of Calcium citrate is more easily absorbed,
calcium exist. These include: seaweeds easier to digest and less likely to cause
such as kelp, wakame and hijiki; nuts and constipation and gas than calcium
seeds (like almonds and sesame); beans; carbonate. It also has a lower risk of
seafood such as oysters and shrimp; contributing to the formation of kidney
soft-boned fish; amaranth; whole wheat; stones. Calcium citrate is 21% elemental
collard greens; okra; rutabaga; broccoli; calcium. 1000 mg will provide 210 mg of
and fortified products such as orange calcium. It is more expensive than
juice and bread. calcium carbonate and more of it must be
Other uses include: as a reducing agent taken to get the same amount of calcium.
in the extraction of other metals, such Calcium phosphate costs more than calcium
as uranium, zirconium, and thorium. carbonate, but less than calcium citrate.
as a deoxidizer, desulfurizer, or It is easily absorbed and is less likely
decarbonizer for various ferrous and to cause constipation and gas than
nonferrous alloys. either.
as an alloying agent used in the Calcium lactate and calcium aspartate are
production of aluminium, beryllium, both more easily digested, but more
copper, lead, and magnesium alloys. expensive than calcium carbonate.
in the making of cements and mortars to Disorders of calcium metabolism occur
be used in construction. when the body has too little or too much
History Calcium (Latin calcis, meaning calcium. The serum level of calcium is
"lime") was known as early as the first closely regulated within a fairly limited
century when the Ancient Romans prepared range in the human body.
lime as calcium oxide. It was not The amount of biologically active calcium
actually isolated until 1808 in England varies with the level of albumin, a
when Sir Humphrey Davy electrolyzed a protein to which calcium is bound, and
mixture of lime and mercuric oxide. Davy therefore levels of ionized calcium are
was trying to isolate calcium and when he better measures than a total calcium;
heard that Berzelius and Pontin prepared however, one can correct a total calcium
calcium amalgam by electrolyzing lime in if the albumin level is known. When you
mercury, he tried it himself. He worked don't have enough calcium your bones
with electrolysis throughout his life and become weak and very fragile.
also discovered/isolated magnesium, A normal ionized calcium is 1.12-1.45
strontium and barium. mmol/L (4.54-5.61 mg/dL).
Compounds Calcium, combined with A normal total calcium is 2.2-2.6 mmol/L
phosphate to form hydroxylapatite, is the (9-10.5 mg/dl).
mineral portion of human and animal bones Total calcium of less than 8.0 mg/dL is
and teeth. The mineral portion of some hypocalcaemia, with levels below 1.59
corals can also be transformed into mmol/L (6 mg/dL) generally fatal.
hydroxylapatite. Total calcium of more than 11.111 mg/dL
Calcium oxide (lime) is used in many is hypercalcaemia, with levels over 3.753
chemical refinery processes and is made mmol/L (15.12 mg/dL) generally fatal.






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